Published November 23, 1977 | Version v1
Journal article Metadata-only

Deuterium isotope effects in the solvolysis of benzal halides. 3. β-D3 isotope effects and the mechanism of solvolysis of 1,1-dihaloethylbenzenes in dioxane-water mixtures

Creators

  • 1. Univ. of Maryland, Baltimore

Description

The β-D3 isotope effects and product distributions in the solvolysis of 1,1-dihaloethylbenzenes in dioxane--water mixtures were determined. The reaction yields two products and the rate-limiting step was determined. The factors determining the extent of elimination reactions are discussed

Additional details

Identifiers

DOI
10.1021/ja00466a075;

Publishing Information

Journal Title
Journal of the American Chemical Society
Journal Volume
99
Journal Issue
24
Series
J. Am. Chem. Soc.
Journal Page Range
8093-8095
ISSN
0002-7863

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
9378408
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AROMATICS; CHEMICAL REACTION KINETICS; DEUTERIUM; ISOTOPE EFFECTS; SOLVOLYSIS
Descriptors DEC
CHEMICAL REACTIONS; DECOMPOSITION; HYDROGEN ISOTOPES; ISOTOPES; KINETICS; LIGHT NUCLEI; NUCLEI; ODD-ODD NUCLEI; ORGANIC COMPOUNDS; REACTION KINETICS; STABLE ISOTOPES

Optional Information

Notes
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