Published July 18, 2011 | Version v1
Journal article Metadata-only

Facile conversion of CO/H2 into methoxide at a uranium(III) center

Creators

  • 1. Division of Chemistry, School of Life Sciences, University of Sussex, Brighton (United Kingdom)
  • 2. LPCNO, INSA Toulouse (France)

Description

Hydrogenation of CO: The reaction of [U(η-C8H6{SiiPr3-1,4}2)(η-Cp*)] in toluene with CO and H2 at subambient to ambient temperature and pressure affords the methoxide complex [U(η-C8H6{SiiPr3-1,4}2)(η-Cp*)OMe]. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Availability note (English)

Available from: http://dx.doi.org/10.1002/anie.201101509

Additional details

Identifiers

DOI
10.1002/anie.201101509;

Publishing Information

Journal Title
Angewandte Chemie (International Edition)
Journal Volume
50
Journal Issue
30
Journal Page Range
p. 6881-6883
ISSN
1433-7851
CODEN
ACIEF5

INIS

Country of Publication
Germany
Country of Input or Organization
Germany
INIS RN
48046103
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBON MONOXIDE; HYDROGENATION; ORGANOMETALLIC COMPOUNDS; SYNTHESIS GAS; URANIUM COMPOUNDS; X-RAY DIFFRACTION
Descriptors DEC
ACTINIDE COMPOUNDS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; COHERENT SCATTERING; DIFFRACTION; FLUIDS; GASES; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SCATTERING

Optional Information

Notes
With 5 figs., 17 refs.