Magnetic properties of the carbides Y2ReC2, Tb2ReC2, Er2ReC2 and Lu2ReC2
- 1. Institut Max von Laue - Paul Langevin, 38 - Grenoble (France)
- 2. Laboratoire Leon Brillouin (CNRS-CEA), Centre d' Etudes de Saclay, F-91191, Gif-sur-Yvette Cedex (France)
- 3. Anorganisch-Chemisches Institut, Universitaet Muenster, Wilhelm-Klemm-Str. 8, D-48149, Muenster (Germany)
Description
Magnetic susceptibility measurements with a SQUID magnetometer reveal that the rhenium atoms in Y2ReC2 and Lu2ReC2 do not carry magnetic moments. The moments of the lanthanoid atoms in Tb2ReC2 and Er2ReC2 order antiferromagnetically below TN=96(2) and 18(1) K, respectively. Both compounds show metamagnetic transitions, and above the Neel temperatures strong field-dependent paramagnetism was observed suggesting strong paramagnetic anisotropies. The antiferromagnetic structures of both compounds are different, however, with the same propagation vector k=0. They were determined from neutron powder data recorded in zero field at 1.5 K. The magnetic structures can be described with the basis functions [0, Ay, 0] and [Gx, Ay, Az] for the terbium and erbium moments, respectively, using Bertaut's representation analysis. (orig.)
Additional details
Publishing Information
- Journal Title
- Journal of Magnetism and Magnetic Materials
- Journal Volume
- 151
- Journal Issue
- 1-2
- Journal Page Range
- p. 273-282.
- ISSN
- 0304-8853
- CODEN
- JMMMDC
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- Netherlands
- INIS RN
- 27018868
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- ANTIFERROMAGNETIC MATERIALS; ERBIUM CARBIDES; HYSTERESIS; LUTETIUM CARBIDES; MAGNETIC MOMENTS; MAGNETIC PROPERTIES; NEEL TEMPERATURE; NEUTRON DIFFRACTION; RHENIUM CARBIDES; TERBIUM CARBIDES; YTTRIUM CARBIDES
- Descriptors DEC
- CARBIDES; CARBON COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; ERBIUM COMPOUNDS; LUTETIUM COMPOUNDS; MAGNETIC MATERIALS; MATERIALS; PHYSICAL PROPERTIES; RARE EARTH COMPOUNDS; RHENIUM COMPOUNDS; SCATTERING; TERBIUM COMPOUNDS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPOUNDS; TRANSITION TEMPERATURE; YTTRIUM COMPOUNDS