Published November 2005 | Version v1
Journal article Metadata-only

Synthesis, crystal structure, and IR spectrum of hexamolybdocobaltate(III) with the copper ammonia complex cation [Cu(NH3)4] · H[CoMo6O18(OH)6] · 10H2O

Creators

  • 1. Univ. Autonoma Metropolitana - Azcapotzaico, Mexico (Mexico)
  • 2. Moskovskij Gosudarstvennyj Pedagogicheskij Univ., Moscow (Russian Federation)
  • 3. Inst. Fizicheskoj Khimii im. L.Ya. Karpova, Moscow (Russian Federation)
  • 4. Inst. Politecnico Nacional, Mexico (Mexico)

Description

Copper ammonia hydrogen hexamolybdocobaltate(III), [Cu(NH3)4] · H[CoMo6O18(OH)6] · 10H2O, was first synthesized and studied by monocrystal X-ray diffraction. The crystals are monoclinic, space group C2/c, a = 24.259(5) A, b = 10.997(2) A, c = 11.559(2) A, β=107.82(3) deg, ρcalcd = 2.907 g/cm3, FW = 1282.41, Z = 4, V=2930(1) A3. The compound was studied by X-ray powder diffraction, thermogravimetric analysis, and IR spectroscopy

Abstract (Russian)

Впервые синтезирован и исследован методом рентгеноструктурного анализа кислый медно-аммиачный гексамолибденокобальтат(III) состава [Сu(NН3)4] · H[СоМо6О18(ОН)6] · 10H2O. Кристаллы моноклинные, пр. гр. С2/с, а = 24.259(5), b = 10.997(2), с = 11.559(2) А, β=107.82(3) град, ρвыч = 2.907 г/см3, М = 1282.41, Z = 4, V = 2930(1) А3. Соединение изучено методами рентгенофазового и термогравиметрического анализа, а также ИК-спектроскопии

Additional details

Additional titles

Original title (Russian)
Синтез, кристаллическая структура и IK-спектр гексамолибденокобальтата(III) с медно-аммиачным комплексным катионом состава [Cу(NH

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
50
Journal Issue
11
Journal Page Range
p. 1813-1818
ISSN
0044-457X
CODEN
ZNOKAQ

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
37049613
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AMMONIA; BOND ANGLE; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COBALT COMPLEXES; COPPER COMPLEXES; HYDRATES; HYDROXIDES; INFRARED SPECTRA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MOLYBDENUM COMPLEXES; MONOCLINIC LATTICES; PYROLYSIS; THERMAL GRAVIMETRIC ANALYSIS
Descriptors DEC
CHEMICAL ANALYSIS; CHEMICAL REACTIONS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DECOMPOSITION; DISTANCE; GRAVIMETRIC ANALYSIS; HYDRIDES; HYDROGEN COMPOUNDS; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; OXYGEN COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SPECTRA; SYNTHESIS; THERMAL ANALYSIS; THERMOCHEMICAL PROCESSES; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
21 refs., 4 figs., 4 tabs.