Published July 1992 | Version v1
Journal article

Relation between temperature coefficient of surface tension and fusion entropy

Creators

  • 1. Moskovskij Gosudarstvennyj Univ., Moscow (Russian Federation)

Description

A new model for calculating temperature coefficient of surface tension (TKST) of single-component liquids is suggested. The surface liquid layer is considered as elastic film, that is as solid phase. It enables to conclude, that surface entropy of liquid, which is equal to TKST, is proportional to melting entropy of the given substance. Calculations of TKST for different metals in approximation of monolayer structure of the surface layer were conducted and equation was derived. Calculations correspond satisfactorily with experimental data for many metals (especially for alkali ones)

Additional details

Additional titles

Original title (Russian)
Связ' температурного коэффициента поверхностного натяжения с энтропией плавления

Publishing Information

Journal Title
Zhurnal Fizicheskoj Khimii
Journal Volume
66
Journal Issue
7
Journal Page Range
p. 1946-1948.
ISSN
0044-4537
CODEN
ZFKHA9

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
25051029
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CESIUM; CORRELATIONS; ENTROPY; LIQUID METALS; SURFACE TENSION; TEMPERATURE COEFFICIENT
Descriptors DEC
ALKALI METALS; ELEMENTS; FLUIDS; LIQUIDS; METALS; PHYSICAL PROPERTIES; REACTIVITY COEFFICIENTS; SURFACE PROPERTIES; THERMODYNAMIC PROPERTIES