Published 2017 | Version v1
Journal article Metadata-only

Crystal structure of heterometallic cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] and K4.4Cs1.6[Re3Mo3S8(CN)5]

Creators

  • 1. Russian Academy of Sciences, Novosibirsk (Russian Federation). Nikolaev Inst. of Inorganic Chemistry
  • 2. Novosibirsk National Research State Univ. (Russian Federation)

Description

Rhenium-molybdenum cluster compounds K5.3Rb0.7[Re3Mo3S8(CN)5] (1) and K4.4Cs1.6[Re3Mo3S8(CN)5] (2) are obtained by the interaction of an equimolar mixture of ReS2 and MoS2 with molten KCN and RbI/CsCl, respectively. The structure of the complexes is determined by the XRD method. The compounds crystallize in the tetragonal crystal system, space group I4/m. The crystal structure is composed of anionic chains of [Re3Mo3S8(CN)4(CN)2/2]6- aligned along the a crystallographic axis and M+ cations located in voids of the lattice. The effect of additional Cs+ and Rb+ cations on the crystallographic parameters and geometric characteristics of the clusters is analyzed.

Availability note (English)

Available from: http://dx.doi.org/10.1134/S0022476617010292

Additional details

Identifiers

DOI
10.1134/S0022476617010292;

Publishing Information

Journal Title
Journal of Structural Chemistry
Journal Volume
58
Journal Issue
1
Journal Page Range
p. 203-206
ISSN
0022-4766
CODEN
JSTCAM

INIS

Country of Publication
United States
Country of Input or Organization
Germany
INIS RN
49076352
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CESIUM COMPOUNDS; CRYSTAL STRUCTURE; CYANIDES; MOLYBDENUM COMPLEXES; POTASSIUM COMPOUNDS; RHENIUM COMPLEXES; RUBIDIUM COMPOUNDS; SULFUR COMPOUNDS; SYNTHESIS; TETRAGONAL LATTICES; X-RAY DIFFRACTION
Descriptors DEC
ALKALI METAL COMPOUNDS; COHERENT SCATTERING; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; SCATTERING; THREE-DIMENSIONAL LATTICES; TRANSITION ELEMENT COMPLEXES