Published November 13, 2019 | Version v1
Report

Evaluation of Thermolytic Production of Hydrogen from Glycolate and Common Tank Farm Organics in Simulated Waste

  • 1. Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Laboratory (SRNL)

Description

The Savannah River National Laboratory (SRNL) has performed testing to investigate the thermolytic production of hydrogen gas from organic species present in the Savannah River Site (SRS) Concentration, Storage, and Transfer Facilities (CSTF). SRNL designed an experimental apparatus to measure the time-dependent concentration of hydrogen in the headspace over a reacting mixture of simulated caustic waste media and organic compounds as well as a methodology to calculate a steady-state hydrogen generation rate (HGR) from this data. Special focus was given to glycolate, which is not currently present in CSTF waste but will be contained in the recycle stream from the Defense Waste Processing Facility (DWPF) under the upcoming alternate reductant flowsheet.

Availability note (English)

Available from https://www.osti.gov/servlets/purl/1576214; https://www.osti.gov/biblio/1576214; DOE Accepted Manuscript full text, or the publishers Best Available Version will be available free of charge after the embargo period

Additional details

Publishing Information

Imprint Pagination
130 p.
Report number
SRNL-STI--2019-00605

Optional Information

Contract/Grant/Project number
AC09-08SR22470
Funding organization
USDOE Office of Environmental Management - EM (United States)
Secondary number(s)
OSTIID--1576214