Infrared-laser-induced organic reactions. Technical progress report
Description
Experiments of two types have been conducted. In the first, competition among activation, deactivation, and unimolecular chemical reaction in laser-irradiated organic vapors were investigated. The following compounds were studied: vinycyclopropane; bicyclopropyl and bicyclopropyl-d4; diethylcarbonate-d5. As an outgrowth of these experiments, single photon vibrational overtone excitation of t-butyl hydroperoxide was initiated. In the second phase of this program, infrared laser activation of mechanistically more complex reactions were studied. These were laser-induced decomposition of 2-propanol catalyzed by CuO, and laser-induced decomposition of oxetane. Results are discussed
Availability note (English)
MF available from INIS under the Report Number; Available from NTIS., PC A02/MF A01 as DE83000285.
Files
Restricted
The record is publicly accessible, but files are restricted to users with access.
Additional details
Additional titles
- Augmented title (English)
- Vinycyclopropane; bicyclopropyl and bicyclopropyl-d_4; diethylcarbonate-d_5; t-butyl hydroperoxide; oxetane; 2-propanol
Publishing Information
- Imprint Pagination
- 11 p.
- Report number
- DOE/ER/10592--3
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 14736114
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Progress Report
- Descriptors DEI
- CARBON DIOXIDE LASERS; CARBONIC ACID DERIVATIVES; COPPER OXIDES; CYCLOALKANES; DEUTERIUM COMPOUNDS; INFRARED SPECTRA; ORGANIC OXYGEN COMPOUNDS; PEROXIDES; PHOTOCHEMISTRY; PROPANOLS; PULSED IRRADIATION; RESEARCH PROGRAMS
- Descriptors DEC
- ALCOHOLS; ALKANES; AMPLIFIERS; CHALCOGENIDES; CHEMISTRY; COPPER COMPOUNDS; EQUIPMENT; GAS LASERS; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; IRRADIATION; LASERS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SPECTRA; TRANSITION ELEMENT COMPOUNDS