Published August 1978
| Version v1
Journal article
Photolysis (lambda 185 nm) of liquid tetrahydropyran
- 1. Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany, F.R.). Inst. fuer Strahlenchemie
Description
The main products of the 185 nm photolysis of neat liquid tetrahydropyran are pent-4-en-1-ol (phi = 0.40), 2-(5'-hydroxypentyl)tetrahydropyran (0.21), valeraldehyde (0.13), and pentan-1-ol (0.08). These products are thought to be formed via the biradical .(period on line)O(CH2)4CH2, and/or through intramolecular and intermolecular photoreactions. In the case of the 2nd product, the probability of a specific intermolecular photoreaction involving two tetrahydropyran molecules is suggested by the fact that in the photolysis of solutions of tetrahydropyran in cyclohexane and formaldehyde dimethyl acetal products analogous to the 2nd product made up of a tetrahydropyran and a solvent molecule moiety, are not formed. (orig./HK)
Abstract (German)
Die Hauptprodukte der 185 nm-Photolyse von fluessigem Tetrahydropyran sind Pent-4-en-1-ol (phi = 0,40), 2-(5'-Hydroxypentyl)tetrahydropyran (0,21), Valeraldehyd (0,13) und Pentan-1-ol (0,08). Man nimmt an, dass diese Produkte ueber das Biradikal .(period on line)O(CH2)4CH2 und/oder durch intra- und intermolekulare Photoreaktion entstehen. Beim zweiten Produkt wird die Wahrscheinlichkeit einer spezifischen intermolekularen Photoreaktion, an der zwei Tetrahydropyranmolekuele beteiligt sind, durch die Tatsache unterstuetzt, dass bei der Photolyse von Loesungen von Tetrahydropyran in Cyclohexan und Formaldehyd Dimethylacetalprodukte anolog zum zweiten Produkt, das aus Tetrahydropyran und einer Loesungsmittelmoelekuelhaelfte besteht, nicht gebildet werden. (orig.)Additional details
Additional titles
- Augmented title (English)
- Teil IX der Reihe: Radiation Chemistry of Ethers. Teil VIII s. R. Bausch, H.P. Schuchmann, C. von Sonntag, R. Benn, und H. Dreeskamp, J. Chem. Soc. Chem. Commun. 1976, 418-419
Publishing Information
- Journal Title
- Z. Naturforsch., B
- Journal Volume
- 33
- Journal Issue
- 8
- Series
- Z. Naturforsch., B.
- Journal Page Range
- 942-945
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 10436496
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALCOHOLS; ALDEHYDES; CHEMICAL REACTION YIELD; COMPARATIVE EVALUATIONS; ETHERS; IRRADIATION; PHOTOLYSIS; RADIATION CHEMISTRY; RADICALS; TETRAHYDROPYRAN
- Descriptors DEC
- CHEMICAL REACTIONS; CHEMISTRY; DECOMPOSITION; HETEROCYCLIC COMPOUNDS; HYDROXY COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PYRANS
Optional Information
- Notes
- Part IX of the series: Radiation Chemistry of Ethers. For Part VIII see R. Bausch, H.P. Schuchmann, C. von Sonntag, R. Benn, and H. Dreeskamp, J. Chem. Soc. Chem. Commun. 1976, 418-419.