Published December 1989 | Version v1
Journal article Metadata-only

Interaction of ruthenium chlorocomplexes with dimethyl sulfoxide

Creators

  • 1. Moskovskij Inst. Tonkoj Khimicheskoj Tekhnologii, Moscow (USSR)

Description

Methods of EAS (electron absorption spectroscopy) and ESR are used to study interaction of ruthenium chlorocomplexes with dimethyl sulfoxide (DMSO). It is shown that K3[RuCl6] and K2[RuH2OCl5] complexes are dissolved in DMSO with formation of ruthenium(3) chlorodimethyl sulfoxide complex, characterized by ESR and electron absorption spectra. Ruthenium reduction up to +2 oxidation degree with formation of [RuDMSO4Cl2] complex takes place. When K2[RuCl6] is dissolved in DMSO, initial [RuCl6]2- ion is preserved for a long time in a solution along with formation of ruthenium(3) chlorodimethyl sulfoxide complex. Comparative analysis of interaction of ruthenium chloro- and bromocomplexes with DMSO is carried out

Additional details

Additional titles

Original title (Russian)
Взаимодействие хлорокомплексов рутения с диметилсульфоксидом

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
34
Journal Issue
12
Series
Zh. Neorg. Khim.
Journal Page Range
3073-3076
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21082004
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHLORIDES; DMSO; ELECTRON SPECTRA; ELECTRON SPIN RESONANCE; HYDRATES; POTASSIUM COMPOUNDS; REDUCTION; RUTHENIUM COMPLEXES
Descriptors DEC
ALKALI METAL COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; HALIDES; HALOGEN COMPOUNDS; KINETICS; MAGNETIC RESONANCE; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; REACTION KINETICS; RESONANCE; SPECTRA; SULFOXIDES; TRANSITION ELEMENT COMPLEXES