Published June 1983
| Version v1
Journal article
Investigation of complexing equilibria of molybdenyl-ion with nitrate- and chlorate ions on the basis of catalytic polarographic oxidant currents
Creators
- 1. Vsesoyuznyj Nauchno-Issledovatel'skij Inst. Khimicheskikh Reaktivov i Osobo Chistykh Veshchestv, Moscow (USSR)
Description
A study was made on processes of Mo(6) complexing with nitrate- and chlorate ions from their catalytic polarographic reduction currents in solutions of sulfuric, perchloric and mandelic acids. Constants of molybdenum (6) complexing with nitrate ions MoO22+HNO3- (K--2.1 lxmol-1) with bisulfate ion MoO22+xHSO4- (K2=0.9 lxmol-1) as well as equilibrium constants of ion-exchange of NO3- and ClO3- for HSO4 in the studied complexes and constants of intracomplex oxidation rate: Mo3+ to Mo5+ with nitrate ion (k=(1400+-40)lxmol-1xs-1) and Mo5+ to Mo6+ with chlorate ion(k=1.1x108 lxmol-1xs-1), were calculated
Additional details
Additional titles
- Original title (Russian)
- Исследование равновесий комплексообразования молибденил-иона с нитрат- и хлорат-ионами на основе каталитических полярографических токов окислителей
Publishing Information
- Journal Title
- Zh. Neorg. Khim.
- Journal Volume
- 28
- Journal Issue
- 6
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 1471-1476
- ISSN
- 0044-457X
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 15035377
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CHLORATES; MOLYBDENUM COMPLEXES; NITRATES; OXIDATION; SULFATES
- Descriptors DEC
- CHEMICAL REACTIONS; CHLORINE COMPOUNDS; COMPLEXES; HALOGEN COMPOUNDS; KINETICS; NITROGEN COMPOUNDS; OXYGEN COMPOUNDS; REACTION KINETICS; SULFUR COMPOUNDS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- For English translation see the journal Russian Journal of Inorganic Chemistry (UK).