Published September 1979 | Version v1
Journal article

Single crystals with compositions in the range TiBsub(1.89) - TiBsub(1.96) prepared by chemical transport

  • 1. Ecole Nationale Superieure de Chimie, 31 - Toulouse (France)
  • 2. Centre d'Information de Thermodynamique Chimique Minerale, Laboratoire de Thermodynamique et Physico-chimie Metallurgique, Associe au Centre National de la Recherche Scientifique, Saint Martin d'Heres (France)

Description

Chemical vapour transport appears to be a suitable method for growing TiB2 single crystals. In the present work the influence of the transporting agent was especially investigated. By both experimentation and thermodynamic calculations the authors determined suitable growth conditions for using I2, BI3, TeCl4 and BBr3 as transporting agents. For similar quantities of transporting agent and temperature range the transport reaction can be endothermic or exothermic, and variable amounts of diboride are transported. (Auth.)

Additional details

Publishing Information

Journal Title
J. Less-Common Met.
Journal Volume
67
Journal Issue
1
Series
J. Less-Common Met.
Journal Page Range
107-114
ISSN
0022-5088

Conference

Title
6. International symposium on boron and borides.
Dates
9 - 12 Oct 1978.
Place
Varna, Bulgaria.

INIS

Country of Publication
Switzerland
Country of Input or Organization
Switzerland
INIS RN
11530940
Subject category
S36: MATERIALS SCIENCE;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
CHEMICAL COMPOSITION; CHEMICAL VAPOR DEPOSITION; CRYSTAL GROWTH; EXPERIMENTAL DATA; MONOCRYSTALS; TABLES; TITANIUM BORIDES; VERY HIGH TEMPERATURE
Descriptors DEC
BORIDES; BORON COMPOUNDS; CHEMICAL COATING; CRYSTALS; DATA; DATA FORMS; DEPOSITION; INFORMATION; NUMERICAL DATA; SURFACE COATING; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS