Influence of Boron on Austenite to Ferrite Transformation Behavior of Low Carbon Steel Under Continuous Cooling

In the current work, the influence of boron on austenite to ferrite transformation behavior under continuous cooling condition and its associated features, e.g., final microstructure, mechanical properties, etc., in low carbon steel has been studied. The steels (C 0.04 wt.%, B 10-100 ppm) prepared in an open air laboratory furnace showed identical microstructures having ferrite grains of 20-25 µm. However, tensile test data indicate variation of yield strength and ultimate tensile strength with boron content. The yield point elongation and strain aging index both were found to decrease with increase in boron content or boron-to-nitrogen ratio. As the boron nitride precipitates stimulate the nucleation of ferrite phase, the dilation curves show an increase in austenite to ferrite transformation start temperature with boron content. The resulting microstructure and hardness value also corroborate the finding. Transmission electron microscopy findings revealed the presence of ultra-fine boron nitride (BN) precipitates in both grain boundary and grain body of the steel having boron concentration of 30 ppm and beyond. The presence of these precipitates also increased with boron content. Based on austenite decomposition behavior, related microstructure and hardness values it is conjectured that these BN precipitates may act as nucleating agent for polygonal ferrite during austenite decomposition, thereby softening the steel during fast cooling.