Published September 2021 | Version v1
Journal article

Improvement of the spectroscopic parameters of the air- and self-broadened N 2 O and CO lines for the HITRAN2020 database applications

  • 1. Atomic and Molecular Physics Division, Harvard-Smithsonian Center for Astrophysics, Cambridge, MA (United States)
  • 2. National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)

Description

This paper outlines the major updates of the line-shape parameters that were performed for the nitrous oxide (N2O) and carbon monoxide (CO) molecules listed in the HITRAN2020 database. We reviewed the collected measurements for the air- and self-broadened N2O and CO spectra to determine proper values for the spectroscopic parameters. Careful comparisons of broadening parameters using the Voigt and speed-dependent Voigt line-shape profiles were performed among various published results for both N2O and CO. Selected data allowed for developing semi-empirical models, which were used to extrapolate/interpolate existing data to update broadening parameters of all the lines of these molecules in the HITRAN database. In addition to the line broadening parameters (and their temperature dependences), the pressure shift values were revised for N2O and CO broadened by air and self for all the bands. The air and self speed-dependence of the broadening parameter for these two molecules were added for every transition as well. Furthermore, we determined the first-order line-mixing parameters using the Exponential Power Gap (EPG) scaling law. These new parameters are now available at HITRANonline.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.jqsrt.2021.107735

Additional details

Identifiers

DOI
10.1016/j.jqsrt.2021.107735;
PII
S0022407321002284;

Publishing Information

Journal Title
Journal of Quantitative Spectroscopy and Radiative Transfer
Journal Volume
271
Journal Page Range
vp.
ISSN
0022-4073
CODEN
JQSRAE

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
54092586
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
CARBON MONOXIDE; LINE BROADENING; MOLECULES; NITRIC OXIDE; NITROUS OXIDE; SCALING LAWS; SPECTRA; TEMPERATURE DEPENDENCE
Descriptors DEC
CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; NITROGEN COMPOUNDS; NITROGEN OXIDES; OXIDES; OXYGEN COMPOUNDS

Optional Information

Copyright
Copyright (c) 2021 Elsevier Ltd. All rights reserved.