Improvement of the spectroscopic parameters of the air- and self-broadened N 2 O and CO lines for the HITRAN2020 database applications
Creators
- 1. Atomic and Molecular Physics Division, Harvard-Smithsonian Center for Astrophysics, Cambridge, MA (United States)
- 2. National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)
Description
This paper outlines the major updates of the line-shape parameters that were performed for the nitrous oxide (NO) and carbon monoxide (CO) molecules listed in the HITRAN2020 database. We reviewed the collected measurements for the air- and self-broadened NO and CO spectra to determine proper values for the spectroscopic parameters. Careful comparisons of broadening parameters using the Voigt and speed-dependent Voigt line-shape profiles were performed among various published results for both NO and CO. Selected data allowed for developing semi-empirical models, which were used to extrapolate/interpolate existing data to update broadening parameters of all the lines of these molecules in the HITRAN database. In addition to the line broadening parameters (and their temperature dependences), the pressure shift values were revised for NO and CO broadened by air and self for all the bands. The air and self speed-dependence of the broadening parameter for these two molecules were added for every transition as well. Furthermore, we determined the first-order line-mixing parameters using the Exponential Power Gap (EPG) scaling law. These new parameters are now available at HITRAN.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jqsrt.2021.107735Additional details
Identifiers
- DOI
- 10.1016/j.jqsrt.2021.107735;
- PII
- S0022407321002284;
Publishing Information
- Journal Title
- Journal of Quantitative Spectroscopy and Radiative Transfer
- Journal Volume
- 271
- Journal Page Range
- vp.
- ISSN
- 0022-4073
- CODEN
- JQSRAE
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 54092586
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- CARBON MONOXIDE; LINE BROADENING; MOLECULES; NITRIC OXIDE; NITROUS OXIDE; SCALING LAWS; SPECTRA; TEMPERATURE DEPENDENCE
- Descriptors DEC
- CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; NITROGEN COMPOUNDS; NITROGEN OXIDES; OXIDES; OXYGEN COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2021 Elsevier Ltd. All rights reserved.