Published March 15, 1980 | Version v1
Journal article Metadata-only

Structure of the fluoride of thallium(I) and uranium(IV)

Creators

  • 1. Clermont-Ferrand-2 Univ., 63 - Aubiere (France)

Description

TlUF5, Msub(r)=518.39, monoclinic, P21/c, a=8.222 (2), b = 13.821 (4), c = 8.317 (5) A, β = 102.53 (3)0, Dsub(m) = 7.42 (5), Dsub(c) = 7.46 Mg m-3, Z = 8. The structure was refined by full-matrix least-squares techniques using data measured on a Nonius CAD-4 automatic diffractometer to an R value of 0.055 for for 1171 independent reflections. The structure consists of sheets perpendicular to the b axis in which each of the two crystallographically independent U ions is nine-coordinated by F atoms in a tricapped trigonal prism arrangement. Tl atoms bind the sheets together. The Tl ions have nine nearest-neighbour F ions. (Auth.)

Additional details

Additional titles

Original title (French)
Structure du fluorure de thallium(I) et d'uranium(IV)

Publishing Information

Journal Title
Acta Crystallogr., Sect. B
Journal Volume
36
Journal Issue
3
Series
Acta Crystallogr., Sect. B.
Journal Page Range
664-666
ISSN
0567-7408

INIS

Country of Publication
Denmark
Country of Input or Organization
Denmark
INIS RN
11530556
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Numerical Data
Descriptors DEI
BOND ANGLE; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; ISOLATED VALUES; LATTICE PARAMETERS; MONOCLINIC LATTICES; SPACE GROUPS; TABLES; THALLIUM FLUORIDES; URANIUM FLUORIDES
Descriptors DEC
ACTINIDE COMPOUNDS; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DATA FORMS; DISTANCE; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; NUMERICAL DATA; SYMMETRY GROUPS; THALLIUM COMPOUNDS; URANIUM COMPOUNDS