Impacts of landscape remediation on the heavy metal pollution dynamics of a lake surrounded by non-ferrous smelter waste

Heavy metal concentrations and potential bioavailability are reported for sediment in a shallow flood detention lake surrounded by reclaimed, smelter-contaminated land. A range of sediment column proxy indicators is used to explore changes in pollution dynamics with remediation. Sediment concentrations of Pb and Zn are high at ∼600 and 20 000 mg kg-1, respectively. Less than 7% of total Pb is potentially bioavailable following sequential extraction as opposed to 47% of Zn. Metal transfer mechanisms to lake sediment include detrital inputs, scavenging by particulates and biogeochemical precipitation. Sedimentary evidence indicates that detrital inputs to the lake declined following land reclamation after which it is proposed that dissolved inputs increased with leaching of reworked waste material. Whilst downcore metal profiles may be subject to post-depositional change, diatom analysis suggests more recent improvements in water quality. The potential for post-remediation pollution episodes relating to metal release from historic sedimentary stores should be considered in future remediation strategies. - The contaminant hydrology of reworked smelter spoil is complex