Transport and leaching of technetium and uranium from spent UO2 fuel in compacted bentonite clay

The transport properties of Tc and U in compacted bentonite clay and the leaching behaviour of these elements from spent nuclear fuel in the same system were investigated. Pieces of spent UO2 fuel were embedded in bentonite clay (ρd=2100 kg/m3). A low saline synthetic groundwater was used as the aqueous phase. After certain experimental times, the bentonite clay was cut into 0.1 mm thick slices, which were analysed for their content of Tc and U. Measurements were made using inductively coupled plasma mass spectrometry. Tc analysis comprised chemical separation. The analysis of U was done by means of detecting 236U, since the natural content of U in bentonite clay made it impossible to distinguish between U originating from the fuel and the clay. The influence of different additives mixed into the clay was studied. The results showed an influence on both transport and leaching behaviour when metallic Fe was mixed into the clay. This indicates that Tc and U are reduced to their lower oxidation states as a result of this additive