Brillouin-scattering study of propylene carbonate: An evaluation of phenomenological and mode coupling analyses
Creators
- 1. Physics Department, City College of the City University of New York, New York, New York 10031 (United States)
- 2. Physik-Department E13, Technische Universitaet Muenchen, 85747 Garching (Germany)
Description
Brillouin-scattering spectra of the molecular glass-forming material propylene carbonate (PC) in the temperature range 140 K to 350 K were analyzed using both the phenomenological Cole-Davidson memory function and a hybrid memory function consisting of the Cole-Davidson function plus a power-law term representing the critical decay part of the fast β relaxation. The spectra were also analyzed using the extended two-correlator schematic mode-coupling theory (MCT) model recently employed by Goetze and Voigtmann to analyze depolarized light backscattering, dielectric, and neutron-scattering spectra of PC [Phys. Rev. E 61, 4133 (2000)]. We assess the ability of the phenomenological and MCT fits, each with three free fitting parameters, to simultaneously describe the spectra and give reasonable values for the α-relaxation time τα
Additional details
Identifiers
- DOI
- 10.1103/PhysRevE.65.051503;
- arXiv
- arXiv:cond-mat/0107503v1;
Publishing Information
- Journal Title
- Physical Review. E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
- Journal Volume
- 65
- Journal Issue
- 5
- Journal Page Range
- p. 051503-051503.17
- ISSN
- 1063-651X
- CODEN
- PLEEE8
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36001758
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- BACKSCATTERING; BRILLOUIN EFFECT; CARBONIC ACID ESTERS; DIELECTRIC MATERIALS; EVALUATION; GLASS; NEUTRON SPECTRA; NEUTRONS; RELAXATION; RELAXATION TIME; TEMPERATURE RANGE 0065-0273 K; TEMPERATURE RANGE 0273-0400 K
- Descriptors DEC
- BARYONS; COHERENT SCATTERING; ELEMENTARY PARTICLES; ESTERS; FERMIONS; HADRONS; MATERIALS; NUCLEONS; ORGANIC COMPOUNDS; SCATTERING; SPECTRA; TEMPERATURE RANGE
Optional Information
- Notes
- (c) 2002 The American Physical Society