Published May 2002 | Version v1
Journal article

Brillouin-scattering study of propylene carbonate: An evaluation of phenomenological and mode coupling analyses

  • 1. Physics Department, City College of the City University of New York, New York, New York 10031 (United States)
  • 2. Physik-Department E13, Technische Universitaet Muenchen, 85747 Garching (Germany)

Description

Brillouin-scattering spectra of the molecular glass-forming material propylene carbonate (PC) in the temperature range 140 K to 350 K were analyzed using both the phenomenological Cole-Davidson memory function and a hybrid memory function consisting of the Cole-Davidson function plus a power-law term representing the critical decay part of the fast β relaxation. The spectra were also analyzed using the extended two-correlator schematic mode-coupling theory (MCT) model recently employed by Goetze and Voigtmann to analyze depolarized light backscattering, dielectric, and neutron-scattering spectra of PC [Phys. Rev. E 61, 4133 (2000)]. We assess the ability of the phenomenological and MCT fits, each with three free fitting parameters, to simultaneously describe the spectra and give reasonable values for the α-relaxation time τα

Additional details

Publishing Information

Journal Title
Physical Review. E, Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Journal Volume
65
Journal Issue
5
Journal Page Range
p. 051503-051503.17
ISSN
1063-651X
CODEN
PLEEE8

Optional Information

Notes
(c) 2002 The American Physical Society