Published 1985 | Version v1
Book Metadata-only

Experimental determination of the H2O+ ground state inversion splitting

Creators

  • 1. Univ. of Chicago, IL

Description

High resolution infrared spectra of the 1- -0+ (10μm), 1+ -0- (20 μm) and 1- -1+ (27 μm) nu2 vibration-inversion bands of H3O+ have been observed in an ac glow discharge by using tunable diode lasers and velocity modulation technique. The three band origins were found to be at 954.4003(25) cm-1, 525.8237(13) cm-1 and 373.2304(47) cm-1, respectively. The rotational and centrifugal distortion constants of these three bands were obtained. From the molecular constants obtained above, the ground state inversion splitting of H3O+ molecular ion has been determined to be 55.3462(55) cm-1

Additional details

Publishing Information

Publisher
Ohio State University.
Imprint Place
Columbus, OH (USA)
Imprint Title
Fortieth symposium on molecular spectroscopy
Journal Page Range
p. 73.

Conference

Title
40. symposium on molecular spectroscopy.
Dates
17-21 Jun 1985.
Place
Columbus, OH (USA).

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
17071751
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S79: ASTROPHYSICS, COSMOLOGY AND ASTRONOMY;
Resource subtype / Literary indicator
Conference, Numerical Data
Descriptors DEI
ABSORPTION SPECTROSCOPY; EXPERIMENTAL DATA; GROUND STATES; HYDRONIUM RADICALS; INFRARED SPECTRA; MEETINGS; MOLECULAR STRUCTURE; SEMICONDUCTOR LASERS; VIBRATIONAL STATES
Descriptors DEC
AMPLIFIERS; DATA; ENERGY LEVELS; EQUIPMENT; EXCITED STATES; INFORMATION; LASERS; NUMERICAL DATA; RADICALS; SEMICONDUCTOR DEVICES; SOLID STATE LASERS; SPECTRA; SPECTROSCOPY