Published August 1, 1974
| Version v1
Journal article
Degenerate perturbation theory
Description
A number of different perturbation formulations found in the literature are discussed. Although these formulations are derived in quite different ways, simple relations among these derivations are described and, in fact, some are shown to yield identical results. One of these degenerate perturbation theories resulting from different formulations due to Van Vleck, Kemble, and Primas, to des Cloizeaux, and to Buleavski is considered in greater detail. Its linked and cluster expansion properties and some other resummation techniques are briefly discussed.
Additional details
Identifiers
- DOI
- 10.1063/1.1682018;
Publishing Information
- Journal Title
- The Journal of Chemical Physics
- Journal Volume
- 61
- Journal Issue
- 3
- Series
- J. Chem. Phys.
- Journal Page Range
- 786-798
- ISSN
- 0021-9606
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 6169578
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ATOMS; ELECTRONIC STRUCTURE; HAMILTONIANS; MOLECULES; PERTURBATION THEORY; ROTATIONAL STATES; SERIES EXPANSION; SHELL MODELS; VIBRATIONAL STATES
- Descriptors DEC
- ENERGY LEVELS; EXCITED STATES; MATHEMATICAL MODELS; MATHEMATICAL OPERATORS; NUCLEAR MODELS; QUANTUM OPERATORS
Optional Information
- Notes
- Updated automatically by Metadata and Full-Text Enrichment Agent