Published September 1987 | Version v1
Journal article Metadata-only

Synthesis and structure of new Na, Zr-phosphate

Creators

  • 1. AN SSSR, Moscow. Inst. Kristallografii

Description

Na9Zn(PO4)4Cl is synthetized and investigated by X-ray analysis, lattice parameters: a=9.151(1), b=9.081(2), c=5.333(1)A, α=90.63(1)deg, Β=91.17(1)deg, γ=111.52(2)deg, V=414.85 A3, Z=1, ρroent=2.855 g/cm3. Mixed linear radicals (Zr(PO4)4) ∞ particle in the compound build-up. Alkali cation is of double crystallochemical character: two of nine Na atoms are included in the three-dimensional frame content, the rest seven atoms fill its emptiness, compensating for negative pseudoframe charge of (Na2ZrP4O16xCl)7-. In this case, the compound structural formula may be presented as Na7(Na2Zr(PO4)4Cl)

Additional details

Additional titles

Original title (Russian)
Синтез и структура нового На, Зр-фосфата

Publishing Information

Journal Title
Kristallografiya
Journal Volume
32
Journal Issue
5
Series
Kristallografiya.
Journal Page Range
1137-1142
ISSN
0023-4761
CODEN
KRISA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
19098586
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL PREPARATION; CHLORIDES; INTERATOMIC DISTANCES; IONIC CONDUCTIVITY; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCRYSTALS; PHOSPHATES; SODIUM COMPOUNDS; TRICLINIC LATTICES; ZIRCONIUM COMPLEXES
Descriptors DEC
ALKALI METAL COMPOUNDS; CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DISTANCE; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; HALIDES; HALOGEN COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; PHYSICAL PROPERTIES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES