Published March 15, 2019 | Version v1
Journal article Metadata-only

Evaluation of Co and Zn competitive sorption by zeolitic material synthesized from fly ash using 60Co and 65Zn as radioindicators

Creators

  • 1. Trnava University in Trnava, Department of Chemistry (Slovakia)
  • 2. University of SS. Cyril and Methodius, Department of Ecochemistry and Radioecology (Slovakia)
  • 3. University of SS. Cyril and Methodius, Department of Chemistry (Slovakia)

Description

Zeolitic material prepared by hydrothermal treatment of brown coal fly ash was used for sorption separation of Co2+ and Zn2+ ions from single and binary solutions. Adsorption in single systems was rapid, pH dependent and follow the Langmuir isotherm. 3D sorption surfaces revealed competitive effects and mutual interactions between Co2+ and Zn2+ and significant preference for Zn2+ in binary system was confirmed. Surface retention and ion-exchange were most probably the principal mechanisms of Co2+ and Zn2+ removal. Zeolitic material with markedly high sorption capacity for Co2+ and Zn2+ can be a promising sorbent for removal of toxic metals and radionuclides.

Additional details

Identifiers

DOI
10.1007/s10967-018-6390-3;

Publishing Information

Journal Title
Journal of Radioanalytical and Nuclear Chemistry
Journal Volume
319
Journal Issue
3
Journal Page Range
p. 855-867
ISSN
0236-5731
CODEN
JRNCDM

INIS

Country of Publication
Hungary
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
54121782
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ADSORPTION; BROWN COAL; COBALT 60; COBALT IONS; EVALUATION; FLY ASH; INTERACTIONS; ION EXCHANGE; PH VALUE; SURFACES; TOXICITY; ZEOLITES; ZINC 65; ZINC IONS
Descriptors DEC
AEROSOL WASTES; ASHES; BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; CARBONACEOUS MATERIALS; CHARGED PARTICLES; COAL; COBALT ISOTOPES; COMBUSTION PRODUCTS; DAYS LIVING RADIOISOTOPES; ELECTRON CAPTURE RADIOISOTOPES; ENERGY SOURCES; EVEN-ODD NUCLEI; FOSSIL FUELS; FUELS; INORGANIC ION EXCHANGERS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTOPES; ION EXCHANGE MATERIALS; IONS; ISOMERIC TRANSITION ISOTOPES; ISOTOPES; MATERIALS; MINERALS; MINUTES LIVING RADIOISOTOPES; NUCLEI; ODD-ODD NUCLEI; RADIOISOTOPES; RESIDUES; SILICATE MINERALS; SORPTION; WASTES; YEARS LIVING RADIOISOTOPES; ZINC ISOTOPES

Optional Information

Copyright
Copyright (c) 2019 Akad#Latin Small Letter E With Acute#miai Kiad#Latin Small Letter O With Acute#, Budapest, Hungary