Published September 15, 1991 | Version v1
Journal article

Electron mobilities in low density hydrogen and carbon monoxide gases: Momentum transfer cross sections at very low energies

  • 1. Chemistry Department, University of Alberta, Edmonton, T6G 2G2 (Canada)

Description

Values of the momentum transfer cross sections σm of hydrogen and carbon monoxide molecules for very low energy electrons (1--300 meV, 0.2--50 zJ; z=zepto=10-21 ) have been refined by electron mobility measurements in the gases over wide ranges of temperature. This is part of an ongoing study of effects of molecular shape on electron transport in fluids. Electron mobilities in hydrogen gas at temperatures 17--450 K are roughly consistent with previously reported values of σm, but do not exclude the possibility of a σm minimum of 5.2x10-20 m2 at an electron energy ξ≤0.7 zJ. Carbon monoxide molecules have a minimum σm of 5.8x10-20 m2 at ξ=5 zJ. A new treatment of low energy electron scattering by CO is needed

Additional details

Publishing Information

Journal Title
Journal of Chemical Physics
Journal Volume
95
Journal Issue
6
Series
J. Chem. Phys.
Journal Page Range
4195-4200
ISSN
0021-9606
CODEN
JCPSA