Published July 2007 | Version v1
Journal article Metadata-only

Acceptor ability of cations in reactions of donor-acceptor interaction

Creators

  • 1. Vserossijskij Nauchno-Issledovatel'skij Inst. Khimichskoj Tekhnologii, Moscow (Russian Federation)
  • 2. Rossijskij Khimiko-Tekhnologicheskij Univ. im. D.I. Mendeleeva, Moscow (Russian Federation)

Description

Analysis of literature data devoted to the problem of quantitative characteristics of cations in reactions of donor-acceptor interaction is represented. Relative acceptor numbers of Co2+, Mn2+, Ni2+, Al3+, Ga3+ are determined by the method of polarography. Known relative acceptor numbers for 21 cations are systematized and linear dependence between ionization potentials and relative acceptor numbers of the rigid cations is determined

Abstract (Russian)

Представлен анализ литературных данных, посвященных проблеме количественной характеристики реакционной способности катионов в реакциях донорно-акцепторного взаимодействия. Методом полярографии определены относительные акцепторные числа Co2+, Mn2+, Ni2+, Al3+, Ga3+. Систематизированы известные относительные акцепторные числа для 21 катиона и установлена линейная зависимость между потенциалами ионизации и относительными акцепторными числами жестких катионов

Additional details

Additional titles

Original title (Russian)
Акцепторная способность катионов в реакциях донорно-акцепторного взаимодействия

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
77
Journal Issue
7
Journal Page Range
p. 1057-1063
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
39003851
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BERYLLIUM COMPLEXES; BINDING ENERGY; CHEMICAL BONDS; CHEMICAL REACTIONS; INDIUM COMPLEXES; POLAROGRAPHY; RARE EARTH COMPLEXES; SCANDIUM COMPLEXES; SOLVATION; STRONTIUM COMPLEXES; THORIUM COMPLEXES; VALENCE; YTTRIUM COMPLEXES; ZIRCONIUM COMPLEXES
Descriptors DEC
ACTINIDE COMPLEXES; ALKALINE EARTH METAL COMPLEXES; COMPLEXES; ENERGY; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
35 refs., 4 tabs.