Efficient degradation of butylparaben by gamma radiolysis

Gamma radiolysis and ozonolysis are two competitive advanced oxidation processes for degradation of organic pollutants present in the ground water. In this paper, the gamma radiolytic degradation of an emerging organic pollutant Butylparaben (BP) in aqueous solution has been investigated for the first time at different absorbed doses. The effect of the absorbed dose rate in the degradation and mineralization of BP has been investigated. About 65% mineralization of BP was observed at absorbed dose of 70 kGy and dose rate of 0.7 kGy h⁻¹. Interestingly, turbidity appeared in the solution during radiolysis at doses higher than 2 kGy, which disappeared again at very higher dose (~90 kGy) making the solution again transparent. At lower dose rate of 0.175 kGy h⁻¹ the turbidity was appeared at much lower dose about 1 kGy. However, the dose rate showed no effect in the dose of the disappearance of the turbidity. The hydrophobic fragments insoluble in water were generated during the initial stage of gamma radiolysis and those were completely mineralized to CO₂ and H₂O by direct absorption of gamma radiation. About 90 kGy dose was required to achieve ~90% mineralization of BP. On the contrary, maximum 50% mineralization was achieved after 5 h of ozonation at the O₃ flow rate of 0.5 L min⁻¹ at pH 7.5 and it remained even constant upon prolonged ozonation. The oxygen-equivalent-chemical-oxidation-capacity (OCC) was used as the parameter to compare the % mineralization efficiencies of the two oxidative processes studied here and the gamma radiolysis was found to be more efficient between those processes. The phytotoxicity of the treated BP solution to agricultural seeds showed that the radiolytically generated fragments were less toxic compared to ozonolytically generated fragments. Thus gamma radiolysis is effective for reducing the organic burden and the toxicity of water polluted with emerging pollutants like BP. - Highlights: • First report on the gamma radiolytic mineralization of butyl paraben. • The gamma radiolysis consumes lesser amount of oxidant compared to ozonolysis for mineralization of BP. • The radiolytically treated solution was proved to be lesser toxic compared to ozonolytically treated solution.