Published October 1989
| Version v1
Journal article
HoAl3Cl12 in crystalline form
Description
The chemical transport of lanthanoid halides via the gas phase is possible, for example, with AlCl3. Spectroscopic investigations have revealed the formation of the 'gas complexes' LnAl3Cl12 and LnAl4Cl15. The holmium-containing title compound has now been characterized by X-ray structure analysis. HoAl3Cl12 contains square HoCl8 antiprisms edge-linked with AlCl4 tetrahedra, resulting in the overall formation of screw-shaped chains. (orig.)
Additional details
Publishing Information
- Journal Title
- Angewandte Chemie. International Edition in English
- Journal Volume
- 28
- Journal Issue
- 10
- Series
- Angew. Chem. Int. Ed. Engl.
- Journal Page Range
- 1364-1365
- ISSN
- 0570-0833
- CODEN
- ACIEA
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 21013270
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALUMINIUM CHLORIDES; CHEMICAL PREPARATION; CRYSTAL STRUCTURE; GASES; HOLMIUM CHLORIDES; HOLMIUM COMPLEXES; REACTION PRODUCT TRANSPORT
- Descriptors DEC
- ALUMINIUM COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; COMPLEXES; FLUIDS; HALIDES; HALOGEN COMPOUNDS; HOLMIUM COMPOUNDS; RARE EARTH COMPLEXES; RARE EARTH COMPOUNDS; SYNTHESIS