Published January 10, 2005 | Version v1
Journal article

Chemical generation of iodine atoms

  • 1. Directed Energy Directorate, Air Force Research Laboratory, 3550 Aberdeen Avenue SE, Kirtland AFB, NM 87117-5776 (United States)
  • 2. Northrup Grumman Information Technology, Science and Technology Operating Unit, Advanced Technology Division, P.O. Box 9377, Albuquerque, NM 87119-9377 (United States)

Description

The chemical generation of atomic iodine using a chemical combustor to generate the atomic fluorine intermediate, from the reaction of F2 + H2, followed by the production of atomic iodine, from the reaction of F + HI, was investigated. The maximum conversion efficiency of HI into atomic iodine was observed to be approximately 75%, which is in good agreement with the theoretical model. The conversion efficiency is limited by the formation of iodine monofluoride at the walls of the combustor where the gas phase temperature is insufficient to dissociate the IF

Additional details

Identifiers

DOI
10.1016/j.chemphys.2004.08.012;
PII
S0301-0104(04)00476-8;

Publishing Information

Journal Title
Chemical Physics
Journal Volume
308
Journal Issue
1-2
Journal Page Range
p. 159-169
ISSN
0301-0104
CODEN
CMPHC2

INIS

Country of Publication
Netherlands
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
36081383
Subject category
S74: ATOMIC AND MOLECULAR PHYSICS;
Descriptors DEI
CHEMICAL PREPARATION; FLUORINE; HYDRIODIC ACID; HYDROGEN; IODINE; IODINE LASERS
Descriptors DEC
ELEMENTS; GAS LASERS; HALOGEN COMPOUNDS; HALOGENS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IODINE COMPOUNDS; LASERS; NONMETALS; SYNTHESIS

Optional Information

Copyright
Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.