Published January 10, 2005
| Version v1
Journal article
Chemical generation of iodine atoms
- 1. Directed Energy Directorate, Air Force Research Laboratory, 3550 Aberdeen Avenue SE, Kirtland AFB, NM 87117-5776 (United States)
- 2. Northrup Grumman Information Technology, Science and Technology Operating Unit, Advanced Technology Division, P.O. Box 9377, Albuquerque, NM 87119-9377 (United States)
Description
The chemical generation of atomic iodine using a chemical combustor to generate the atomic fluorine intermediate, from the reaction of F2 + H2, followed by the production of atomic iodine, from the reaction of F + HI, was investigated. The maximum conversion efficiency of HI into atomic iodine was observed to be approximately 75%, which is in good agreement with the theoretical model. The conversion efficiency is limited by the formation of iodine monofluoride at the walls of the combustor where the gas phase temperature is insufficient to dissociate the IF
Additional details
Identifiers
- DOI
- 10.1016/j.chemphys.2004.08.012;
- PII
- S0301-0104(04)00476-8;
Publishing Information
- Journal Title
- Chemical Physics
- Journal Volume
- 308
- Journal Issue
- 1-2
- Journal Page Range
- p. 159-169
- ISSN
- 0301-0104
- CODEN
- CMPHC2
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 36081383
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- CHEMICAL PREPARATION; FLUORINE; HYDRIODIC ACID; HYDROGEN; IODINE; IODINE LASERS
- Descriptors DEC
- ELEMENTS; GAS LASERS; HALOGEN COMPOUNDS; HALOGENS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IODINE COMPOUNDS; LASERS; NONMETALS; SYNTHESIS
Optional Information
- Copyright
- Copyright (c) 2004 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.