Published 2015 | Version v1
Book Metadata-only

Complexation of Ln3+ and Am3+ with 2,6-bis-(tetrazol-5-yl)pyridine (BTzP): UV-Vis spectrophotometry and DFT studies

Creators

  • 1. Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai (India)
  • 2. Bio-Organic Division, Bhabha Atomic Research Centre, Mumbai (India)

Description

Complexation of Am3+ and several Ln3+ ions was studied with a new class of tridentate acidic 'N' donor ligand 2,6-Bis-(tetrazol-5-yl)pyridine (BTzP) using UV-Vis spectrophotometric titrations. Formation of higher stoichiometric complex with very high formation constant in case of Am3+ indicates the selectivity of this ligand towards trivalent actinides over the lanthanides. (author)

Part of:
Proceedings of the twelfth DAE-BRNS national symposium on nuclear and radiochemistry

Additional details

Publishing Information

Publisher
Board of Research in Nuclear Sciences
Imprint Place
Mumbai (India)
Imprint Title
Proceedings of the twelfth DAE-BRNS national symposium on nuclear and radiochemistry
Imprint Pagination
700 p.
Journal Page Range
p. 257-258

Conference

Title
12. DAE-BRNS national symposium on nuclear and radiochemistry
Acronym
NUCAR-2015
Dates
9-13 Feb 2015
Place
Mumbai (India)

INIS

Country of Publication
India
Country of Input or Organization
India
INIS RN
46089644
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
AMERICIUM COMPLEXES; DENSITY FUNCTIONAL METHOD; LANTHANUM COMPLEXES; PYRIDINES; SPECTROPHOTOMETRY; STRUCTURAL CHEMICAL ANALYSIS
Descriptors DEC
ACTINIDE COMPLEXES; AZINES; CALCULATION METHODS; COMPLEXES; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RARE EARTH COMPLEXES; TRANSURANIUM COMPLEXES; VARIATIONAL METHODS

Optional Information

Notes
3 refs., 3 figs., 2 tabs.