On the temperature dependent magnetic properties of as-spun Mn–Bi ribbons

The structural and magnetic properties of melt-spun ribbons with nominal composition of Mn₅₅Bi₄₅ were investigated using X-ray diffraction, transmission electron microscopy and magnetometer measurements. A large coercivity (H_c) of 0.8 T was observed in the as-spun ribbons. Microstructure reveals the presence of Mn–Bi nanoparticles in the as-spun ribbons. Coercivity was found to increase with increasing temperature with a maximum coercivity of 1.4 T at T=503 K in the as-spun ribbons. Heat treatment of the as-spun ribbons resulted in the increase of LTP MnBi phase. Spin reorientation transition (T_SR) was observed around 100 K. - Highlights: • Mn–Bi system by melt spinning • Coercivity increases with temperature • The LTP phase increases with heat treatment