Published February 1978
| Version v1
Journal article
Distinguishing axial and equatorial carbonyl groups in iron pentacarbonyl by ESCA
- 1. Univ. of California, Berkeley
Description
Gas phase spectra were recorded for iron carbonyl. The raw spectra were analyzed using the nonlinear least-squares fitting program GAMET. The spectral data are in qualitative agreement with the prediction that the equatorial oxygen atoms are more negatively charged than the axial oxygen atoms. It is also indicated that the back-bonding to the equatorial CO groups is greater than that to the axial CO groups
Additional details
Publishing Information
- Journal Title
- Inorg. Chem.
- Journal Volume
- 17
- Journal Issue
- 2
- Series
- Inorg. Chem.
- Journal Page Range
- 489-491
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 9394205
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- No Abstract
- Descriptors DEI
- CARBONYLS; ELECTRON SPECTROSCOPY; IRON COMPOUNDS; MOLECULAR STRUCTURE
- Descriptors DEC
- SPECTROSCOPY; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- Published in summary form only.