Published September 1992
| Version v1
Journal article
Radiolysis of benzene solutions of cobalt(II) acetylacetonate
- 1. M.V. Lomonosov Moscow State Univ. (Russian Federation)
Description
The formation of gaseous products of the gamma radiolysis of benzene in the presence of Co(acac)2 was studied, and the radiation-chemical yields of hydrogen, acetylene methane, and ethylene were determined. Spectrophotometric data showed that, as a result of irradiation, oxidation of the additive occurred, with formation of cobalt(III) complexes. Yields of biphenyl and phenylcyclohexadienes were determined in these benzene solutions, and also in systems containing Co(acac)2 with 18-crown-6. Possible mechanisms of the processes taking place are discussed. 10 refs., 2 tabs
Additional details
Publishing Information
- Journal Title
- High Energy Chemistry
- Journal Volume
- 26
- Journal Issue
- 2
- Journal Page Range
- p. 79-81.
- ISSN
- 0018-1439
- CODEN
- HIECAP
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 27061543
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- BENZENE; COBALT COMPLEXES; GAMMA RADIATION; RADIOLYSIS
- Descriptors DEC
- AROMATICS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; COMPLEXES; DECOMPOSITION; ELECTROMAGNETIC RADIATION; HYDROCARBONS; IONIZING RADIATIONS; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; TRANSITION ELEMENT COMPLEXES
Optional Information
- Notes
- Cover-to-cover Translation of Khimiya Vysokikh Energii (USSR); Translated from Khimiya Vysokikh Energii; 26: No. 2, 104-106(Mar-Apr 1992).