Published May 2000 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of sodium trans-nitroso-aquatetrachlororuthenate(2)

Creators

  • 1. SO RAN, Inst. Neorganichesloj Khimii, Novosibirsk (Russian Federation)

Description

A method of Na[RuNOCl4H2O] · 2H2O compound synthesis is described. The complex is studied by the methods of IR spectroscopy, X-ray phase and X-ray diffraction analyses. Crystallographic data are as follows: a = 7.0103(7), b = 11.133(1), c = 12.843(1) A, β = 99.076(8) Deg, sp. gr. P21/n, Z = 4, dcal = 2.348, dexp = 2.340 g/cm3. The structure is made up by [RuNOCl4H2O]- complex anions, Na+ cations and crystallization water molecules. The compound is crystallized very slowly, after a long allowance to stand of saturated aqueous solution as adhesions of claret colour. The crystals are moisture-absorbing and diffuse when kept in the air

Abstract (Russian)

Описана методика синтеза соединения Na[RuNOCl4Н2O] · 2H2O. Комплекс исследован методами ИК спектроскопии, рентгеновского и рентгеноструктурного анализа. Кристаллографические данные: a = 7.0103(7), b 11.133(1), c = 12.843(1) A, β = 99.076(8) град, пр. гр. P21/n, Z = 4, dвыч = 2.348, dэксп = 2.340 г/см2. Структура построена из комплексных анионов [RuNOCl4H2O]-, катионов Na+ и молекул кристаллизационной воды. Соединение кристаллизуется очень медленно, после длительного стояния насыщенного водного раствора в виде сростков бордового цвета. Кристаллы гигроскопичны и расплываются при хранении на воздухе

Additional details

Additional titles

Original title (Russian)
Синтез и кристалличская структура транс-нитрозоакватетрахлорорутената(2) натрия

Publishing Information

Journal Title
Zhurnal Strukturnoj Khimii
Journal Volume
41
Journal Issue
3
Journal Page Range
p. 567-571
ISSN
0136-7463
CODEN
ZSTKAI

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32019263
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; CHLORIDES; DEHYDRATION; DENSITY; HYDRATES; INFRARED SPECTRA; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; NITROUS OXIDE; RUTHENIUM COMPLEXES; SODIUM COMPOUNDS
Descriptors DEC
ALKALI METAL COMPOUNDS; CHALCOGENIDES; CHLORINE COMPOUNDS; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; HALIDES; HALOGEN COMPOUNDS; NITROGEN COMPOUNDS; NITROGEN OXIDES; OXIDES; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; TRANSITION ELEMENT COMPLEXES; YIELDS

Optional Information

Notes
6 refs., 3 figs., 2 tabs.