Published June 1994
| Version v1
Journal article
Interaction of ruthenium dimethylsulfoxide complexes with HBr
Creators
- 1. Moscovskaya Gosudarstvennaya Akademiya Tonkoj Khimicheskoj Tekhnologii im. Lomonosova, Moscow (Russian Federation)
Description
The behaviour of ruthenium (2) dimethylsulfoxide complexes-cis- and trans-[Ru)DMSO)4X2) and ruthenium (3)-[DMSO)2H][Ru(DMSO)2X4] (X=Cl, Br) was studied in concentrated HBr by absorption electron spectra technique. Interaction with HBr at room temperature causes deoxygenation of DMSO and formation of ruthenium dimethyl sulfoxide complexes and then substitution of intra spherical ligands with [RuBr2]3- formation. As this takes place, ruthenium (2) complexes are oxidized to ruthenium (3) complexes. At the same time the total transition to [RuBr7]3- at Cru>10-5 mol/l is not available. 20 refs
Additional details
Additional titles
- Original title (Russian)
- Взаимодействие диметилсульфоксидных комплесов рутения с NBr
Publishing Information
- Journal Title
- Zhurnal Neorganicheskoj Khimii
- Journal Volume
- 39
- Journal Issue
- 6
- Journal Page Range
- p. 925-928.
- ISSN
- 0044-457X
- CODEN
- ZNOKAQ
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 26075644
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL COMPOSITION; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; DMSO; HYDROBROMIC ACID; RUTHENIUM COMPLEXES
- Descriptors DEC
- BROMINE COMPOUNDS; COMPLEXES; HALOGEN COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; REACTION KINETICS; SULFOXIDES; TRANSITION ELEMENT COMPLEXES