Impact of $\mathrm{CaC}{l}_2$-induced chemical pressure on the phase transition of $H_{2}O$ at high pressure

Understanding the phase behavior and structural properties of salt water at high pressures is essential for understanding the dynamics and physical characteristics of icy planets. In this study, we employed high-pressure experimental and ab initio simulation techniques to investigate the impact of $\mathrm{CaC}{l}_2$ on the structure of ice VII. Our findings reveal that 1.8 mol% $\mathrm{CaC}{l}_2$ can be incorporated into the ice VII structure above 10 GPa. This $\mathrm{CaC}{l}_2$-bearing ice VII (Cb VII) exhibits a lower O-H stretching frequency in the Raman spectra as well as a reduced volume of the unit cell compared to pure ice VII. In contrast to doping ice VII with other salts such as LiCl and NaCl that leads to an increase of the ice VII to ice X transition pressure occurring at 100–150 GPa, $\mathrm{CaC}{l}_2$ doping stands out by reducing the transition pressure. It shifts the transition to a pressure of 52 GPa, which is significantly lower than the transition pressure of 80 GPa in the pure $H_{2}O$ ice system. This notable distinction highlights the unique influence of $\mathrm{CaC}{l}_2$ on the phase behavior of water under high pressure, and we attribute these effects to the phenomenon of chemical pressure induced by $\mathrm{CaC}{l}_2$ within the ice VII structure. Our study suggests that the presence of a modified ice VII phase, contaminated with salt and referred to as Cb VII, may influence the composition, structure, and evolution of planets.