Published February 15, 1985 | Version v1
Journal article

Direct solution of the H(1s)--H+ long-range interaction problem in momentum space

Creators

  • 1. Departments of Applied Chemistry and Applied Science for Energy, Muroran Institute of Technology, Muroran, Hokkaido, 050 Japan

Description

Perturbation equations for the H(1s)--H+ long-range interaction are solved directly in momentum space up to the fourth order with respect to the reciprocal of the internuclear distance. As in the hydrogen atom problem, the Fock transformation is used which projects the momentum vector of an electron from the three-dimensional hyperplane onto the four-dimensional hypersphere. Solutions are given as linear combinations of several four-dimensional spherical harmonics. The present results add an example to the momentum-space solution of the nonspherical potential problem

Additional details

Publishing Information

Journal Title
J. Chem. Phys.
Journal Volume
82
Journal Issue
4
Series
J. Chem. Phys.
Journal Page Range
2022-2025
ISSN
0021-9606