Source term for the bounding assessment of the Canadian nuclear fuel waste disposal concept

This is the second in a series to derive the bounds of the post-closure hazard of the Canadian nuclear fuel waste disposal concept, based on the premise that it is unnecessary to predict accurately the real hazard if the bounding hazard can be shown to be acceptable. In this report a reference used (Bruce A fuel, 865 GJ/kgU average burnup) is used to derive the source term for contaminant releases from the emplacement canisters. This requires development of a container failure function which defines the age of the fuel when the canister is perforated and flooded. The source term is expressed as the time-dependent fractional release rate from the used fuel or as the time-dependent contaminant concentrations in the canister porewater. It is derived as the superposition of an instant release, comprising the upper bound of the gap and grain boundary inventory in the used fuel, and the long-term dissolution of the used fuel matrix. Several dissolution models (stoichiometric dissolution/preferential leaching) under different conditions (matrix solubility limited/ unlimited; oxidizing/ reducing solubility limits; groundwater flow/ no flow) are evaluated and the one resulting in the highest release rate/ highest porewater concentration is adopted as the bounding case. Comparisons between the models are made on the basis of the potential ingestion hazard of the canister porewater, to account for differences in the hazard of different radionuclides. (author) 20 refs., 4 tabs., 9 figs