Published January 1995 | Version v1
Journal article

Ion-built-in covalent-cyclic model in the MNDO calculations of intermolecular interactions in heterogeneous systems

  • 1. Volgogradskij Gosudarstvennyj Univ., Volgograd (Russian Federation)

Description

The MNDO calculation scheme has been modified for the case of a cyclic cluster model for periodic infinite structure (polymers, crystals). Two methods of presetting cyclic boundary conditions are suggested. In the framework of the approximations suggested an expression for total energy of ion-built-in covalent-cyclic cluster, required for optimization of geometry of objects simulated, has been obtained. The method has been used for the calculation of boron nitride hexagonal structure. 21 refs.; 2 tabs

Additional details

Additional titles

Original title (Russian)
Модел' ионно-встроенного ковалентно-циклического кластера в MNDO-расчетах межмолекулярных взаимодействий в генетрогенных системах

Publishing Information

Journal Title
Zhurnal Fizicheskoj Khimii
Journal Volume
69
Journal Issue
1
Journal Page Range
p. 189-192.
ISSN
0044-4537
CODEN
ZFKHA9