Published May 12, 2009
| Version v1
Journal article
Synthesis of nanocrystalline titanium nitride at low temperature and its thermal stability
- 1. Nanomaterials and Chemistry Key Laboratory, Advanced Materials Research Center of Wenzhou, Wenzhou University, Wenzhou, Zhejiang 325027 (China)
- 2. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325027 (China)
- 3. City College, Wenzhou University, Wenzhou, Zhejiang 325035 (China)
Description
Nanocrystalline titanium nitride has been prepared via a convenient route by the reaction of metallic magnesium powder with titanium dioxide and ammonium chloride in an autoclave at 650 deg. C. X-ray powder diffraction pattern indicated that the product was cubic titanium nitride, and the cell constant was a = 4.261 A. Transmission electron microscopy (TEM) image showed that it consisted of particles with an average size of about 30 nm in diameter. The product was also studied by BET and TGA. It had good thermal stability and oxidation resistance below 350 deg. C in air.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.jallcom.2008.09.048Additional details
Identifiers
- DOI
- 10.1016/j.jallcom.2008.09.048;
- PII
- S0925-8388(08)01526-0;
Publishing Information
- Journal Title
- Journal of Alloys and Compounds
- Journal Volume
- 476
- Journal Issue
- 1-2
- Journal Page Range
- p. 603-605
- ISSN
- 0925-8388
- CODEN
- JALCEU
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 41018605
- Subject category
- S77: NANOSCIENCE AND NANOTECHNOLOGY;
- Descriptors DEI
- AMMONIUM CHLORIDES; CRYSTALS; MAGNESIUM; NANOSTRUCTURES; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; TITANIUM NITRIDES; TITANIUM OXIDES; TRANSMISSION ELECTRON MICROSCOPY; X-RAY DIFFRACTION
- Descriptors DEC
- ALKALINE EARTH METALS; AMMONIUM COMPOUNDS; AMMONIUM HALIDES; CHALCOGENIDES; CHEMICAL ANALYSIS; CHLORIDES; CHLORINE COMPOUNDS; COHERENT SCATTERING; DIFFRACTION; ELECTRON MICROSCOPY; ELEMENTS; GRAVIMETRIC ANALYSIS; HALIDES; HALOGEN COMPOUNDS; METALS; MICROSCOPY; NITRIDES; NITROGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PNICTIDES; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; THERMAL ANALYSIS; TITANIUM COMPOUNDS; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2008 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.