Published January 2000 | Version v1
Journal article Metadata-only

The solid-state interaction of organometallic aldehydes with 1,8-naphthylenediamine

Creators

  • 1. RAN, Inst. Ehlementorganicheskikh Soedinenij im. A.N. Nesmeyanova, Moscow (Russian Federation)

Description

The solid-state interaction between equimolar mixture of ruthenocenecarbaldehyde and 1,8-naphthylenediamine was studied by 1NMR at room temperature. It is found that colourless crystals of 2-ruthenocenyl-2,3-dihydroperimidine, its melting point is 203-204 Deg C, form with a chemical reaction yield of 87 % upon holding the reaction mixture for 16 days under above mentioned conditions

Abstract (Russian)

Методом ЯМР 1Н изучено твердофазное взаимодействие рутеноценкарбальдегида с 1,8-нафтилендиамином при комнатной температуре и эквимолярном соотношении реагентов. Установлено, что при выдерживании реакционной смеси в указанных выше условиях в течение 16 суток с выходом 87 % образуются бесцветные кристаллы 2-рутеноценил-2,3-дигидроперимидина, имеющего температуру плавления 203-204 град С

Additional details

Additional titles

Original title (Russian)
Твердофазное взаимодействие металлорганических альдегидов с 1,8-нафтилендиамином

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
Journal Issue
no.1
Journal Page Range
p. 145-146
ISSN
1026-3500
CODEN
IASKEA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
32002945
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALDEHYDES; AMINES; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; CONDENSED AROMATICS; DIENES; MELTING POINTS; NMR SPECTRA; PROTONS; RUTHENIUM COMPLEXES; SOLIDS
Descriptors DEC
AROMATICS; BARYONS; CATIONS; CHARGED PARTICLES; COMPLEXES; ELEMENTARY PARTICLES; FERMIONS; HADRONS; HYDROCARBONS; HYDROGEN IONS; HYDROGEN IONS 1 PLUS; IONS; KINETICS; NUCLEONS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; POLYENES; REACTION KINETICS; SPECTRA; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES; TRANSITION TEMPERATURE; YIELDS

Optional Information

Notes
10 refs., 1 tab.