Published July 1977 | Version v1
Journal article

Electronic structure of permanganate-ion and GrO42-, VO43- isoelectronic ions from X-ray spectra

Creators

  • 1. AN SSSR, Novosibirsk. Inst. Neorganicheskoj Khimii

Description

Electron structure of VO43-, CrO42-, MnO4- isoelectron ions has been considered on the base of the analysis of x-ray emission- and x-ray absorption spectra with taking account of relaxation effects. Experimental energy values of engaged and free valent molecular orbitals of complexes have been given. The composition of valent molecular orbitals has been analyzed. X-ray spectrum and x-ray electron investigation results have been compared to the theoretical calculations of the complexes

Additional details

Additional titles

Original title (Russian)
Электронная структура перманганат-иона и изоэлектронных с ним ионов CrO

Identifiers

Publishing Information

Journal Title
Journal of Structural Chemistry
Journal Volume
18
Journal Issue
4
Series
Zh. Strukt. Khim.
Journal Page Range
483-494
ISSN
0022-4766

Conference

Title
Roentgenoelectronic and roentgen spectra and electronic structure of metals, alloys and chemical compounds.
Dates
7 - 10 Sep 1976.
Place
Sverdlovsk, USSR.

INIS

Country of Publication
USSR
Country of Input or Organization
USSR
INIS RN
9404158
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
ABSORPTION SPECTRA; ANIONS; COMPARATIVE EVALUATIONS; ELECTRONIC STRUCTURE; EMISSION SPECTRA; ENERGY LEVELS; LCAO METHOD; VANADATES; X-RAY SPECTRA
Descriptors DEC
CHARGED PARTICLES; IONS; OXYGEN COMPOUNDS; SPECTRA; TRANSITION ELEMENT COMPOUNDS; VANADIUM COMPOUNDS

Optional Information

Notes
For English translation see the journal J. Struct. Chem.; Updated automatically by Metadata and Full-Text Enrichment Agent