Published 1975 | Version v1
Journal article

Thermochemistry of trivalent metal compounds of iron group

Creators

  • 1. Krasnodarskij Politekhnicheskij Inst. (USSR)

Description

Standard heats of formation (ΔH2980) of theMeO.nH20 hydroxides were computed from the formula ΔH2980 = ΔHsub(298)sup(0(Meo) 71.n. Heats of formation of the Me(OH)2 and Me(OH)3 hydroxides were estimated, where Me is the iron group transition metal. Satisfactory agreement of the experimenta and theoretical data enabled to compute the values ΔH2980 of Co2O3 and Ni2O3 from the heats of formation of Co(OH)3 and Ni(OH)3. Using the values ΔHsub(298)sup(0(Me2O3)) heats of formation of the MeOOH hydroxides are computed. The values ΔH2980 for FeOOH and β=NiOOH agree with experimental data available

Additional details

Additional titles

Original title (Russian)
Термохимия соединений трехвалентных металлов группы железа

Publishing Information

Journal Title
Izv. Vyssh. Uchebn. Zaved., Chern. Metall.
Journal Issue
no.10
Series
Izv. Vyssh. Uchebn. Zaved., Chern. Metall.

INIS

Country of Publication
USSR
Country of Input or Organization
USSR
INIS RN
10422961
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
IRON COMPOUNDS
Descriptors DEC
TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
For selective English translation see the journal Stal USSR.