Published September 1995
| Version v1
Journal article
Kinetics of technetium reactions. XIII. Reduction of Tc(VII) with hydroxyethylhydrazine
Creators
- 1. Bochvar All-Russian Research Institute of Inorganic Materials, Moscow (Russian Federation)
Description
2-Hydroxethylhydrazine reduces Tc(VII) to Tc(IV) with formation of TcCl-5 ions. The rate of this reaction in HCl solution obeys the equation -d[Tc(VII)]/ dt = k[Tc(VII)][HOC2H4N2H+4]0.9[H+]1.4, where k = (8.75 ±0.46) x 10-3 12.3 mol-2.3 min-1 at 25 degrees C and μ = 3.1. The reaction mechanism is similar to that of the reaction of Tc(VII) with unsubstituted hydrazine
Additional details
Publishing Information
- Journal Title
- Radiochemistry (New York)
- Journal Volume
- 37
- Journal Issue
- 5
- Journal Page Range
- p. 381-383.
- ISSN
- 1066-3622
- CODEN
- RDIOEO
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 27025011
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- CHEMICAL REACTION KINETICS; ORGANIC NITROGEN COMPOUNDS; OXIDATION; REDUCTION; TECHNETIUM
- Descriptors DEC
- CHEMICAL REACTIONS; ELEMENTS; KINETICS; METALS; ORGANIC COMPOUNDS; REACTION KINETICS; TRANSITION ELEMENTS
Optional Information
- Notes
- Translated from Radiokhimiya; 37: No. 5, 415-417(1995).