Published March 2003
| Version v1
Journal article
Calcination of frequencies and forms of normal vibrations of neodymium biglycinate
Creators
- 1. Kubanskij Gosudarstvennyj Univ., Krasnodar (Russian Federation)
Description
The results of the X-ray structural, IR and CR spectroscopic studies on the neodymium dimer complex of the (NdCl3·2HGl·3H2O)2 composition, where HGl = N+H3CH2COO-, are presented. The fragmentation calculation of the frequencies and forms of the normal vibrations constituting the complete description of the experimental vibration spectra is accomplished. The set of the force constants of the neodymium dimer complex, which may be applied by the theoretical analysis of the vibration spectra of the rare earth complexes with the α-amino acids is presented
Abstract (Russian)
Приведены результаты рентгеноструктурного, ИК и КР спектроскопических исследований димерного комплекса неодима состава NdCl3·2HGl·3H2O)2, где HGl = N+H3CH2COO-. Выполнен пофрагментарный расчет частот и форм нормальных колебаний, дающий полное описание экспериментальных колебательных спектров. Представлен набор силовых констант димерного комплекса неодима, которые могут быть использованы при теоретическом анализе колебательных спектров комплексов редкоземельных элементов с α-аминокислотамиAdditional details
Additional titles
- Original title (Russian)
- Расчет частот и форм нормальных колебаний биглицината неодима
Publishing Information
- Journal Title
- Zhurnal Strukturnoj Khimii
- Journal Volume
- 44
- Journal Issue
- 2
- Journal Page Range
- p. 338-342
- ISSN
- 0136-7463
- CODEN
- ZSTKAI
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 36038131
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHLORIDES; DIMERS; GLYCINE; HYDRATES; INFRARED SPECTRA; MOLECULAR STRUCTURE; NEODYMIUM COMPLEXES; RAMAN SPECTRA; STRENGTH FUNCTIONS; VIBRATIONAL STATES
- Descriptors DEC
- AMINO ACIDS; CARBOXYLIC ACIDS; CHLORINE COMPOUNDS; COMPLEXES; ENERGY LEVELS; EXCITED STATES; FUNCTIONS; HALIDES; HALOGEN COMPOUNDS; ORGANIC ACIDS; ORGANIC COMPOUNDS; RARE EARTH COMPLEXES; SPECTRA
Optional Information
- Notes
- 11 refs., 1 fig., 3 tabs.