Published November 19, 2008 | Version v1
Journal article

Stability of the fcc structure in block copolymer systems

  • 1. Department of Mathematical and Life Sciences, Graduate School of Sciences, Hiroshima University, 1-3-1 Higashi-Hiroshima, 739-8526 (Japan)

Description

The stability of the face-centered cubic (fcc) structure in microphase separated copolymers is investigated by a coarse-grained approach. Direct simulations of the equation for the microphase separation in three dimensions indicate that there is a narrow area above a certain degree of segregation in the phase diagram, where the fcc structure is the most stable structure. By employing the mode expansion, we have confirmed that the fcc structure can form as a metastable structure even in the weak segregation regime.

Availability note (English)

Available from http://dx.doi.org/10.1088/0953-8984/20/46/465104

Additional details

Identifiers

DOI
10.1088/0953-8984/20/46/465104;
PII
S0953-8984(08)83489-3;

Publishing Information

Journal Title
Journal of Physics. Condensed Matter
Journal Volume
20
Journal Issue
46
Journal Page Range
[9 p.]
ISSN
0953-8984
CODEN
JCOMEL

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41008304
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
COPOLYMERS; EQUATIONS; EXPANSION; FCC LATTICES; PHASE DIAGRAMS; SEGREGATION; SIMULATION; STABILITY; THREE-DIMENSIONAL CALCULATIONS
Descriptors DEC
CRYSTAL LATTICES; CRYSTAL STRUCTURE; CUBIC LATTICES; DIAGRAMS; INFORMATION; ORGANIC COMPOUNDS; ORGANIC POLYMERS; POLYMERS