Published 1990 | Version v1
Journal article

Magnetoplumbite-related oxides

  • 1. Lab. de Chimie Appliquee de l'Etat Solide, Ecole National Superieure de Chimie de Paris, 11 rue Pierre et Marie Curie, 75005 Paris (France)

Description

These ferrites were prepared from Fe2O3, MO oxides (M = Ba,Sr,Pb) and MeO oxides (Me = Mg,Mn,Co,Zn). Chemical compositions of the main barium ferrites (M = Ba) are represented in a ternary diagram. The structures of these various compounds (M,Y,W,Z,X,U) are closely related. The simplest one is the compound BaFe12O19 (M). Its crystal structure is similar to that of the mineral magnetoplumbite PbFe7.5Mn3.5Al0.5O19 (PbM12O19) (5). For this reason the hexagonal ferrites are also known as magnetoplumbite-type ferrites (called MP-type in this paper). When the Fe3+ ions are replaced by other trivalent ions, such as Al3+, Ga3+, another group of MP-type oxides, namely AB12O19 (A = Ba2+ or a large divalent ion; B = Al3+ or Ga3+) is obtained. In this paper, the authors briefly review ideal structure and major properties and uses, especially in the case of ferrites

Additional details

Publishing Information

Journal Title
Annual Review of Materials Science
Journal Volume
20
Series
Annu. Rev. Mater. Sci.
Journal Page Range
51-82
ISSN
0084-6600
CODEN
ARMSC