Published 1982
| Version v1
Journal article
Application of non-homogeneous kinetics to radical decay in methylcyclohexane-CCl4 in the liquid phase at 142-173 K
Description
The pulse radiolysis of liquid methylcyclohexane containing carbon tetrachloride has been investigated over the temperature range 142 to 173 K. Formation of the CCl4+ cation, the precursor of CCl4.Cl, is accounted for by reaction of CCl4 with the excited methylcyclohexane cation MCH+*. The observed decay of CCl4.Cl and of CCl3 is explained using nonhomogeneous kinetic treatment. Evidence that excited cations play a great role in the radiolysis of hydrocarbons at low temperature is given. (author)
Additional details
Publishing Information
- Journal Title
- Radiat. Phys. Chem.
- Journal Volume
- 20
- Journal Issue
- 5-6
- Series
- Radiat. Phys. Chem.
- Journal Page Range
- 365-368
- ISSN
- 0146-5724
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- United Kingdom
- INIS RN
- 14749281
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- CATIONS; CHEMICAL REACTION KINETICS; CYCLOALKANES; DE-EXCITATION; DECAY; ELECTRONS; EXCITED STATES; G VALUE; LIQUIDS; LOW TEMPERATURE; OPACITY; PULSES; RADIATION DOSES; RADICALS; RADIOLYSIS; TEMPERATURE DEPENDENCE; TETRACHLOROMETHANE
- Descriptors DEC
- ALKANES; CHARGED PARTICLES; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECOMPOSITION; ELEMENTARY PARTICLES; ENERGY LEVELS; ENERGY-LEVEL TRANSITIONS; FERMIONS; FLUIDS; HYDROCARBONS; IONS; KINETICS; LEPTONS; OPTICAL PROPERTIES; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; PHYSICAL PROPERTIES; RADIATION EFFECTS; REACTION KINETICS