Published August 2004 | Version v1
Journal article Metadata-only

Electric-field effect on crystallization in the Li3PO4-Li4GeO4-Li2MoO4-LiF system

Creators

  • 1. RAN, Inst. Kristallografii im. A.V. Shubnikova, Moscow (Russian Federation)

Description

Electric field effect on processes of single crystal growth in the system of Li3PO4-Li4GeO4-Li2MoO4-LiF is studied. It is shown that in the absence of electric field at selected experimental parameters single crystals of Li3=xP1-xGexO4 (x=0.31) grow at the cathode. At U=0.8 V at the cathode the bulk single crystals Li2MoO4 are formed, at U=0.15 V - Li2GeO3. Phosphate-ions do not participate in formation of crystalline phases of the system and are present in the form of a phosphate glass

Abstract (Russian)

Исследовано влияние электрического поля на процессы роста монокристаллов с системе Li3PO4-Li4GeO4-Li2MoO4-LiF. Показано, что без приложения электрического поля при выбранных параметрах эксперимента на катоде растут монокристаллы Li3=xP1-xGexO4 (x=0.31). При U=0.8 В на катоде образуются объемные монокристаллы Li2MoO4, при U=0.15 В - Li2GeO3. Фосфат-ионы не участвуют в формировании кристаллических фаз системы и присутствуют в виде фосфатного стекла

Additional details

Additional titles

Original title (Russian)
Влияние электрического тока на кристаллизацию в системе Ли

Publishing Information

Journal Title
Neorganicheskie Materialy
Journal Volume
40
Journal Issue
8
Journal Page Range
p. 1001-1005
ISSN
0002-337X
CODEN
NEOMB8

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
36110673
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
CHEMICAL COMPOSITION; CRYSTAL GROWTH; ELECTRIC FIELDS; ELECTRIC POTENTIAL; ELECTRODEPOSITION; GERMANATES; LITHIUM FLUORIDES; MOLTEN SALTS; MOLYBDATES; MONOCRYSTALS; PHOSPHATES
Descriptors DEC
ALKALI METAL COMPOUNDS; CRYSTALS; DEPOSITION; ELECTROLYSIS; FLUORIDES; FLUORINE COMPOUNDS; GERMANIUM COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; LITHIUM COMPOUNDS; LITHIUM HALIDES; LYSIS; MOLYBDENUM COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; REFRACTORY METAL COMPOUNDS; SALTS; SURFACE COATING; TRANSITION ELEMENT COMPOUNDS

Optional Information

Notes
9 refs.; 4 figs.; 1 tab.