Published December 2018
| Version v1
Journal article
Catalytic Conversion of Glycerol into Aromatic Hydrocarbons, Acrolein, and Glycerol Ethers on Zeolite Catalysts
Creators
- 1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences (Russian Federation)
Description
The effect of the nature of zeolite catalysts H-ZSM-5, H-BETA, and SAPO-34 on the activity and selectivity in the conversion of glycerol into aromatic hydrocarbons, acrolein, and oxygenates (various glycerol ethers) was studied. H-ZSM-5 was found to be the most effective catalyst for the conversion of glycerol into aromatic hydrocarbons and mono-, di-, and trisubstituted glycerol ethers with methanol and isobutylene. These products are effective gasoline additives increasing its octane number. Zeolite SAPO-34 shows the lowest activity in aromatization and alkylation reactions; the main product formed on this catalyst was acrolein.
Additional details
Identifiers
Publishing Information
- Journal Title
- Russian Journal of Physical Chemistry
- Journal Volume
- 92
- Journal Issue
- 12
- Journal Page Range
- p. 2451-2454
- ISSN
- 0036-0244
- CODEN
- RJPCAR
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 51108931
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- 2-METHYLPROPENE; ACROLEIN; ALKYLATION; ANTIKNOCK RATINGS; AROMATICS; AROMATIZATION; AUGMENTATION; CATALYSTS; ETHERS; FUEL ADDITIVES; GLYCEROL; METHANOL; OCTANE; ZEOLITES
- Descriptors DEC
- ADDITIVES; ALCOHOLS; ALDEHYDES; ALKANES; ALKENES; CHEMICAL REACTIONS; HYDROCARBONS; HYDROXY COMPOUNDS; INORGANIC ION EXCHANGERS; ION EXCHANGE MATERIALS; MATERIALS; MINERALS; ORGANIC COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; SILICATE MINERALS
Optional Information
- Copyright
- Copyright (c) 2018 Pleiades Publishing, Ltd.