Published November 2008 | Version v1
Journal article Metadata-only

Carborane phosphorus-derivatives as ligands for Pd-catalyzed cross-coupling reactions

Creators

  • 1. Inst. Ehlementoorganicheskikh Soedinenij im. A.N. Nesmeyanova Rossijskoj Akademii Nauk, Moscow (Russian Federation)

Description

Synthesis of carborane-containing phosphine ligands possessing different steric and electronic properties has been considered. Testing of the given ligands in Pd-catalyzed Suzuki-Miyaura reaction demonstrated that sterically volume phosphine ligands with acceptor carborane substitutes possessed the most catalytic activity

Abstract (Russian)

Осуществлен синтез карборансодержащих фосфиновых лигандов, обладающих различными cтeрическими и электронными свойствами. Тecтиpoвание данных лигандов в Pd-кaтaлизируемой реакции Сузуки-Мияура показало, что большей каталитической активностью обладают cтeрически объемные фосфиновые лиганды с акцепторными карборановыми заместителями

Additional details

Additional titles

Original title (Russian)
Фосфорпроизводные карборанов как лиганды для Пд-катализируемых реакций кросс-сочетания

Publishing Information

Journal Title
Izvestiya Akademii Nauk. Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
Journal Issue
no.11
Journal Page Range
p. 2262-2265
ISSN
1026-3500
CODEN
IASKEA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
40097476
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CARBORANES; CATALYSIS; CHEMICAL PREPARATION; CHEMICAL REACTIONS; LIGANDS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHOSPHINES; PHOSPHOROUS ACID
Descriptors DEC
CARBON COMPOUNDS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; ORGANIC BORON COMPOUNDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; SYNTHESIS

Optional Information

Notes
13 refs., 2 tabs.