Published 1998 | Version v1
Journal article Metadata-only

Storage of coordination degree of phosphorus atoms in reaction of tetraalkylpyrophosphites with tetraethylammonium tetrafluoroborate

Creators

  • 1. Kazanskij gostekhnologicheskij univ. (Russian Federation)

Description

It is established, that tetraalkylpyrophosphites react with tetraethylammonium tetrafluoroborate in soft conditions in polar aprotic solvent at 25-50 deg or at heating up to 200 deg without solvent. Equi-molar quantities of dialkylfluorophosphite and dialkylethylphosphite are formed with coordination preservation for phosphorus atoms of pyrophosphite equal 3. Mechanism of uncovered reaction is suggested

Additional details

Additional titles

Original title (Russian)
Сохранение степени координации атомов фосфора в реакции тетраалкилпирофосфитов с тетрафторборатом тетраэтиламмония

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
68
Journal Issue
10
Journal Page Range
p. 1653-1655
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
31009227
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BORON FLUORIDES; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHEMICAL REACTIONS; COORDINATION VALENCES; MELTING POINTS; ORGANIC PHOSPHORUS COMPOUNDS; QUATERNARY COMPOUNDS; TEMPERATURE RANGE 0273-0400 K
Descriptors DEC
AMINES; BORON COMPOUNDS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; TEMPERATURE RANGE; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE; VALENCE; YIELDS

Optional Information

Notes
7 refs.